姓名：曹小華

聯(lián)系方式：xiaohuacao@kust.edu.cn

研究方向：

1）含硫揮發(fā)性有機(jī)物催化去除及資源化利用

2）丙烷二氧化碳氧化脫氫

3）二氧化碳加氫甲烷化

個(gè)人簡介：女，1994年出生，陜西延安人，中共黨員，工學(xué)博士，碩士生導(dǎo)師。主要從事大氣污染控制、VOCs催化凈化及資源化利用以及先進(jìn)環(huán)境功能納米材料制備等方面的研究。近五年在Chem. Eng. J., Sep. Purif. Technol., Fuel Process. Technol.以及J. Rare Earth等國際權(quán)威期刊發(fā)表論文20余篇，申請發(fā)明專利3項(xiàng)，主持國家自然科學(xué)基金1項(xiàng)、云南省青年基金1項(xiàng)，獲省部級(jí)科技獎(jiǎng)勵(lì)2項(xiàng)（稀土科學(xué)技術(shù)二等獎(jiǎng)1項(xiàng)、中國有色金屬工業(yè)科學(xué)技術(shù)二等獎(jiǎng)1項(xiàng)）。

工作與教育經(jīng)歷：

2022.08-至今昆明理工大學(xué)，化學(xué)工程學(xué)院，專任教師

2017.09-2022.06昆明理工大學(xué)，環(huán)境工程，工學(xué)博士

2013.09-2017.06延安大學(xué)，環(huán)境科學(xué)，工學(xué)學(xué)士

近五年主要研究項(xiàng)目：

[1]國家自然科學(xué)基金青年基金項(xiàng)目，構(gòu)建非對稱氧空位催化劑應(yīng)用于室溫下甲硫醇催化自氧化脫除機(jī)理研究（批準(zhǔn)號(hào)：22306081），2024.01-2026.12，30萬，在研，主持；

[2]云南省基礎(chǔ)研究專項(xiàng)青年基金項(xiàng)目，淬火誘導(dǎo)合成Co-Ce雙金屬單原子催化劑應(yīng)用于含硫物種的脫除機(jī)理研究（批準(zhǔn)號(hào)：202401AU070136）2024.06-2027.05，5萬，在研，主持；

[3]昆明理工大學(xué)高層次人才引進(jìn)經(jīng)費(fèi)，80萬，2022.09—2030.09，在研，主持；

[4]國家自然科學(xué)基金重點(diǎn)項(xiàng)目，褐煤氣化過程中含硫揮發(fā)性有機(jī)物的排放特征與控制機(jī)理研究（批準(zhǔn)號(hào)：42030712），2021.01—2025.12，296萬，在研，參與（排名第二）；

[5]云南省重大科技專項(xiàng)計(jì)劃，天然橡膠行業(yè)典型污染防治與資源化關(guān)鍵核心技術(shù)研究與應(yīng)用（批準(zhǔn)號(hào)：202202AG050004），2023.01—2025.01，2000萬，在研，參與子課題（排名第三）；

[6]國家自然科學(xué)基金地區(qū)基金項(xiàng)目，液化石油氣中含硫揮發(fā)性有機(jī)物定向轉(zhuǎn)化耦合低碳烷烴脫氫制烯烴的應(yīng)用基礎(chǔ)研究（批準(zhǔn)號(hào)：21966018），2020.01—2023.12，40萬，結(jié)題，參與（排名第四）。

代表性論文：

[1]Zijun Huang,Xiaohua Cao*, Huaiyu Xu, Miao Lin, Dedong He, Dingkai Chen, Jichang Lu*, Yongming Luo*,Revealing low-temperature reaction mechanism of cobalt-doped CeO₂catalyst for catalytic removal of methyl mercaptan,Journal of Rare Earths, 2025,1002-0721.

[2]Huaiyu Xu ,Xiaohua Cao*, Xiude Peng , Miao Lin , Dedong He , Jichang Lu , Dingkai Chen , Yongming Luo*，Catalytic autoxidation of methyl mercaptan at room temperature over three-dimensionally ordered macroporous Cu₂Ce₈O catalyst,Separation and Purification Technology, 2025, 367, 132891.

[3]Zixuan Wang,Xiaohua Cao*, Zijun Huang, Dedong He, Wenwei Wu*, Yongming Luo*, Enhanced sulfur-resistance in Fe-based catalysts with secondary crystallization for the removal of odorous S-VOCs (CH₃SH),Catalysis Today,2024, 439, 114810.

[4]Yuqiu Zhu, Yulai Lin, Jiaming Dong, Jun Liang, Dedong He, Tianhao Ai*,Xiaohua Cao*, Yongming Luo*, Precisely constructing Ce-loaded sulfur resistant catalyst for efficient methane dry reforming,Surfaces and Interfaces, 2024, 50, 104517.

[5]Xiaohua Cao, Tianhao Ai, Zhizhi Xu, Jichang Lu*, Dingkai Chen, Dedong He, Jiangping Liu, Rui Tian, Yutong Zhao, Yongming Luo*, Insights into the different catalytic behavior between Ce and Cr modified MCM-41 catalysts: Cr₂S₃as new active species for CH₃SH decomposition,Separation and Purification Technology, 2023, 307, 122742.

[6]Xiaohua Cao, Jichang Lu*, Xiangqian Zheng, Dedong He, Wenjie Zhu, Yutong Zhao, Wenjun Zhang, Rui Tian, Yongming Luo*, Regulation of the reaction pathway to design the high sulfur/coke-tolerant Ce-based catalysts for decomposing sulfur-containing VOCs,Chemical Engineering Journal, 2022, 429, 132473.

[7]Bihui He, ZhiZhi Xu,Xiaohua Cao*, Jichang Lu*, Jian Fang, Yubei Li, Siyou Feng, Yongming Luo, The influence of lanthanum (La) promoter on Mo/Al₂O₃for the catalytic synthesis of methyl mercaptan (CH₃SH) from COS/H₂/H₂S,Fuel Processing Technology, 2022, 238, 107488.

[8]Xiaohua Cao, Dedong He, Jichang Lu, Yutong Zhao, Yi Mei, Caiyun Han*, Yongming Luo*, The negative effect of P addition of La/HZSM-5 on the catalytic performance in methyl mercaptan abatement,Applied Surface Science, 2019, 494, 1083-1090.

[9]Zijun Huang,Xiaohua Cao, Hao Wang, Dingkai Chen, Xianming Chen, Dedong He, Shuquan Huang*, Yongming Luo*,Ni-doped Co/SPP zeolite catalyst with optimized metal oxide-support interaction for propane dehydrogenation to propylene,Chemical Engineering Journal,2025,511, 162074.

[10]Zijun Huang, Yubing Li*, Yongming Luo*, Dingkai Chen,Xiaohua Cao, Hao Wang, Shuquan Huang, Dedong He*, Boosting propane dehydrogenation performance by engineering of cobalt positions in MFI zeolite,Chemical Engineering Journal,2025,506,160153.

[11]Zijun Huang,Dedong He*,Jichang Lu,Lanfang Han,Kongzhai Li,Dingkai Chen,Xiaohua Cao,Tan Li,Yongming Luo*，Modifying the Charge-Density of Tetrahedral Cobalt(II) Centers through Carbon-Layer Modulation Promotes C-H Activation in the Propane Dehydrogenation Reaction (PDH)，Angewandte Chemie international Edition，2024，1433-7851.

[12]Dedong He, Shaojie Wu,Xiaohua Cao, Dingkai Chen*, Lei Zhang, Yu Zhang, Yongming Luo*, Dynamic trap of Ni atelevated temperature for yielding high-efficiency methane dry reforming catalyst，Applied Catalysis B: Environment and Energy，2024，346，123728.

[13]Dedong He, Yimin Zhang,* Tan Li, Dingkai Chen, Hao Wang, Lei Zhang, Jiangping Liu,Xiaohua Cao, Jichang Lu,* and Yongming Luo*，Designing Ultra-Stable and Surface-Exposed NiNanoparticles with Dually Confined Microenvironment for High-Temperature Methane Dry Reforming，Advanced Functional Materials，2024，12895.

[14]Rui Tian, Jichang Lu*, Zhizhi Xu, Wenjun Zhang, Jiangping Liu, Langlang Wang, Yibing Xie, Yutong Zhao,Xiaohua Cao, and Yongming Luo*. Unraveling the Synergistic Reaction and the Deactivation Mechanism for the Catalytic Degradation of Double Components of Sulfur-Containing VOCs over ZSM-5-Based Materials，Environmental Science Technology, 2023, 57, 3, 1443–1455.

[15]Jiangping Liu, Hong Su, Yanan Hu*, Chenhao Gong, Jichang Lu, Dedong He, Wenjie Zhu, Dingkai Chen,Xiaohua Cao, Jun Li, Sasho Gligorovski, Yongming Luo*, Highly efficient degradation of sulfur-containing volatile organic compounds by amorphous MnO₂at room temperature: Implications for controlling odor pollutants,Applied Catalysis B: Environmental, 2023, 334, 122877.

[16]Yutong Zhao, Dingkai Chen, Jiangping Liu, Dedong He,Xiaohua Cao, Caiyun Han, Jichang Lu*, Yongming Luo*. Tuning the metal-support interaction on chromium-based catalysts for catalytically eliminate methyl mercaptan: Anchored active chromium species through surface hydroxyl groups,Chemical Engineering Journal, 2020, 389, 124384.

發(fā)明專利：

[1]曹小華,徐懷鈺,羅永明,陸繼長,何德東,陳定凱,彭秀德,黃樹全,王皓，一種鈷改性球形氧化鈰催化劑在催化分解甲硫醇中的應(yīng)用（發(fā)明專利，2024年10月31日受理，專利號(hào)：2024115377146）。

[2]羅永明,曹小華,彭秀德,徐懷鈺,陸繼長,何德東,陳定凱,黃樹全,王皓，一種無金屬催化劑在煤氣化過程中催化分解甲硫醇的應(yīng)用（發(fā)明專利，2024年10月31日受理，專利號(hào)：202411538291X）。

[3]何德東,李嘉誠,曹小華,陳定凱,一種聚硅酸鐵鋯絮凝劑在去除污水中的磷酸鹽和氟中的用途（授權(quán)發(fā)明專利，2025年10月03日公開，公開號(hào)：2025100980192）。